Spider-Man
Season 1, Episode 18: The Sinister Prime Minister
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Spider-Man gets into an embassy, sees the foreign visiting Prime Minister tied up and gagged, and fights someone impersonating the Prime Minister, but he is forced to retreat to find proof after being gassed by the imposter's cane and having his camera stolen.
All Episodes - Season 1
Episode 1
The Power of Dr. Octopus
Episode 2
Sub-Zero for Spidey
Episode 3
Where Crawls the Lizard
Episode 4
Electro, the Human Lightning Bolt
Episode 5
The Menace of Mysterio
Episode 6
The Sky Is Falling
Episode 7
Captured by J. Jonah Jameson
Episode 8
Never Step on a Scorpion
Episode 9
Sands of Crime
Episode 10
Diet of Destruction
Episode 11
The Witching Hour
Episode 12
Kilowatt Kaper
Episode 13
The Peril of Parafino
Episode 14
Horn of the Rhino
Episode 15
The One-Eyed Idol
Episode 16
Fifth Avenue Phantom
Episode 17
The Revenge of Dr. Magneto
Episode 18
The Sinister Prime Minister
Episode 19
The Night of the Villains
Episode 20
Here Comes Trubble
Episode 21
Spider-Man Meets Doctor Noah Boddy
Episode 22
The Fantastic Fakir
Episode 23
Return of the Flying Dutchman
Episode 24
Farewell Performance
Episode 25
The Golden Rhino
Episode 26
Blueprint for Crime
Episode 27
The Spider and the Fly
Episode 28
The Slippery Doctor Von Schlick
Episode 29
The Vulture's Prey
Episode 30
The Dark Terrors
Episode 31
The Terrible Triumph of Dr. Octopus
Episode 32
Magic Malice
Episode 33
Fountain of Terror
Episode 34
Fiddler on the Loose
Episode 35
To Catch a Spider
Episode 36
Double Identity
Episode 37
Sting of the Scorpion
Episode 38
Trick or Treachery