Because I Don't Like My Big Brother At-All--!!

Season 1, Episode 2: Twintail, Attacking Brother and Sister

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It turns out that Nao and Shuusuke are not related by blood. While most people would be upset after finding out something like that, Nao took it in the most positive way possible - it meant that there was nothing to get in the way between her and Shuusuke. The next day, a new student named Iroha transfers into Nao's class. At first Nao gets along with her really well, and they even end up having lunch together... but while they are eating Shuusuke comes to give Nao her keys which she left at home. Even though Iroha and Shuusuke should be meeting each other for the first time, Iroha seems strangely interested in him...